We present direct laboratory measurements of the velocity in the airflow above wind generated waves. These data were obtained using optical techniques and thus we were able to measure the velocity within the viscous sublayer above the wavy surface. We observe direct evidence of the separation of this viscous sublayer past the crest of the wind waves. The separation leads to the transport of vorticity away from the surface and the generation of significant mixing. Concurrently, we present the first direct estimate of the surface viscous tangential stress in the airflow. The intermittent separation of the viscous sublayer past the crest of the wind waves leads to dramatic along-wave variability in the surface viscous tangential stress. These results hold for wind speeds that would normally be considered low to moderate. Furthermore, the statistics of separation events correlate with surface wave slope parameters, indicating that, while linear and non-separated models might only be adequate for the very initial stages of the wave generation process and in extreme low wind speed conditions, parameterizations of the mean effects of airflow separation on the total air-sea stress based on surface wave spectra products might be successful approaches.