Here we report the results of a study to develop a physically-based model of the attenuation of atmospheric water vapor fluctuations on the inside walls of closed-path EC sampling tubes during turbulent tube flow for application to the measurement of water vapor (or evapotranspiration) fluxes. The specific goal of this study is to derive a mathematically-simple physically-based transfer function that can be used to correct closed-path EC fluxes for tube attenuation effects. We begin by reviewing observational studies of the attenuation of water vapor fluctuations during turbulent tube flow. We then outline the mathematical statement of this problem and we compare some new models, which we have developed for this study, with previous models. We close with a discussion and formulation of the model boundary conditions at the inside tube wall. This boundary condition, which is based on the adsorptive-desorptive fluxes to the tube wall, is critical to obtaining the desired transfer function because the transfer function is obtained directly from the solution to the mathematical model, which is in turn dictated by the tube wall boundary condition. It should not be surprising that a general formulation of this boundary condition poses a difficult challenge because the physical processes at the tube wall are physiochemical in nature and involve various aspects of the kinetic theory of gases, thin film dynamics, phase changes (condensation and evaporation) on clean homogeneous surfaces and on internal tube surfaces contaminated with atmospheric aerosols, and the dynamics of turbulent tube flow.