for Atmospheric Chartography) on board ENVISAT are assimilated into the Global Modeling
and Assimilation Office (GMAO) constituent assimilation system for the period April 1-October 31, 2004.
SCIAMACHY is a near infrared spectrometer with nearly constant sensitivity to CO in the
Troposphere. As such, retrievals should contain significant information on variability of CO in the boundary layer,
where concentrations are significantly higher.
Carbon monoxide is retrieved from the 2260-2385 nm wavelength band (channel 8), in which the CO line
is relatively weak, and is superimposed by stronger water vapor and temperature lines. This results in
a large fraction of retrievals that are rejected as poor fits to the pre-selected vertical profiles. In
addition, a significant portion of the retrievals are cloud contaminated and the retrievals use a correction
factor from the ratio of retrieved to {\it a priori} methane column. The effect of this correction factor
on the retrieval error statistics is not yet well understood.
In spite of these limitations, initial assimilation results have demonstrated that significant
improvements to estimated CO fields can be made using SCIAMACHY observations. In the present work
we focus on the effect of the variable observation density on spatial variations in the
analysis error, and on improved estimates of observation errors for the cloud contaminated
observations. The former is determined through comparisions with in-situ data from CMDL and MOZAIC,
and we show the relationship between observation density and reduction in the CO field errors. The
cloud contaminated observation errors are estimated by tuning these observation errors separately from
the cloud free observations.
The implications for using SCIAMACHY or other near infrared measurements for source inversion are
are discussed.
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