This study employs over 3 years (May 2008- August 2011) of Global Positioning System (GPS) Radio Occultation (RO) data as a reference to assess and quantify the radiation related biases for sonde types in the global operational radiosonde network. Collocated radiosonde and GPSRO data are collected with the NOAA satellite Products Validation System (NPROVS) operated at the NOAA/NESDIS Center for Satellite Application and Research (STAR). Using the Constellation Observing System for Meteorology Ionosphere & Climate (COSMIC) data as a reference, we analyze the raob-minus-COSMIC temperature differences at different solar elevation angles, seasons, and zonal belts, both for the global radiosonde network and for individual sondes, and evaluate the radiative impact of clouds. The impact of radiosonde radiation error on numerical weather prediction is discussed.