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The results showed that the estimated biogenic isoprene emissions decreased due to reduction of vegetation and forest areas from 1992 to 2010. The air quality simulation results using these emissions and meteorological inputs realized combined effects of biogenic emissions and meteorological changes caused by different LULC data depending on the simulation conditions. In general, simulations predicted ozone concentrations to decrease with the reduced isoprene emissions when temperature increases were not much discernable. However, during the second half of the episode when air temperatures were high and local effects dominated weather, the increases in surface temperature due to the deforestation between 1992 and 2000 were much more apparent. For days from August 30th to September 1st, ozone concentrations increased over and downwind areas of the HGA eight counties in spite of the reduced biogenic emissions for 2000 compared with 1990. The continued decrease in isoprene emissions and little changes in surface temperature resulted in lower ozone concentrations in 2010 than in 2000.
The present study reveals that urban deforestation and subsequent increase of the urban heat island phenomenon result in higher ozone concentrations due to the temperature effects on the air quality. Conversely, if new trees and vegetations with minimal isoprene emissions are planted, the ozone concentrations over and downwind urban areas will be reduced due to the decrease in the urban heat island effects. Moreover, it is expected that the benefits become more effective over the regions with little influence of large direct anthropogenic VOC emission sources, such as the rural and suburban areas downwind of urban and industrial sources.