Thursday, 13 February 2003: 11:15 AM
Sulfate-nitrate-ammonium-water system study of the global troposphere with a size and chemically resolved Aerosol-Chemical Transport Model
Global three dimensional chemically and size-resolved aerosol mass
size distributions are simulated on-line in the Intermediate Model of
Global Evolution of Species (IMAGES). Aerosol-phase thermodynamics
is coupled to this chemical transport model using the Simulating
Composition of Atmospheric Particles at Equilibrium (SCAPE2) module. Nitrate,
ammonium and sulfate concentrations are
calculated using an internally mixed aerosol description. Transport
for both aerosol and gas-phase species is solved using a semi-Lagrangian
scheme driven by monthly mean climatological variables provided by
European Center for Medium-Range Weather Forecasts (ECMWF)
analysis. Aerosols are removed from the atmosphere through
parameterized dry and wet
deposition processes. In addition to precursor gas-phase species, the
thermodynamic module requires prescribed relative humidity and
temperature fields updated monthly by ECMWF analysis. Comparison
between calculated and observed total
aerosol mass concentration fields at selected stations in North
America and Europe fall within a factor of two for most
species. Results suggest that aerosol distributions over continental
polluted areas comprise most of the dry mass over the
accumulation mode, in which sulfate appears to be the dominant
ion. Although not as predominant as sulfate, nitrate seems to be of
importance at least regionally in the present model.
Supplementary URL: