Atmospheric irradiance measurements may be underestimated (up to 12 W/m2 or 5 %) if the influence of instrument temperatures is neglected, even with the artificial ventilation. Preliminary comparisons show that the agreement between measurements and computations increase (a) when a spectral range as broader as possible is taken into account, (b) when the lower atmosphere becomes cooler, and (c) when the integrated water vapor content in lower atmosphere becomes smaller.
Such an investigation is being conducted in the scope of a large research program devoted to the reciprocal influences between air pollution and meteorology at São Paulo. A better understanding of longwave radiative transfer in urban atmospheres could contribute to numerical forecasts of the lower troposphere cooling during the night, and therefore to estimates of atmospheric dispersion conditions.
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