Sub-pixel fractional estimates were highly correlated with the validation dataset at both 4 m and 18 m resolutions. The mean correlations across all 6 cover classes were r2 = 0.82 at 4 m and r2 = 0.75 at 18 m, indicating that imaging spectroscopy was robust enough to conserve fractional estimates across scales, which could be of significant value for urban analysis. As expected, the mean pixel complexity (the number of sub-pixel materials) was higher at 18 m (1.88) than at 4 m (1.65), however 48.0% of all 4 m pixels were estimated to contain sub-pixel mixtures, indicating the value of spectroscopic imagery for producing sub-pixel estimates even at fine spatial scales in cities. The resulting maps of fractional urban composition were then used to examine the relationships between sub-pixel fractions and land surface temperature, with surface temperatures varying significantly along fractional cover gradients. Overall, these results show imaging spectroscopy can provide robust estimates of urban composition fractions across spatial scales. This suggests that the planned satellite acquisition of spectroscopic imagery could provide significant improvements in urban composition mapping that would enable truly global comparative analyses of urban energy and water balances.
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