The profiles show three major episodes within the boundary layer. The strongest of which occurred during the record-setting heat days of 09/4-5, on which winds veering from WNW to NE between 12:00 � 13:00 LT result in peak ozone concentrations of 148 ppb at 900 m over La Marque and surface spikes at Texas City and Galveston near 130 and 150 ppb, respectively. Forward trajectory analysis of the parcels containing the elevated ozone shows a SSW to SW path and boundary layer venting to altitudes as high as 4 km at 6:00 GMT 09/07 near the Texas � Mexico border at Laredo.
Back trajectory analysis of the free troposphere ozone profiles reveals a number of high-and low-ozone regimes. Elevated upper-tropospheric ozone mixing ratios during days 08/21-24 are associated with convective activity over the central United States two days prior in which ozone precursors lifted by the convection, coupled with NOx from lightning were used to �cook� the observed ozone en route.
Elevated middle-tropospheric ozone (0828-09/01) and low upper-tropospheric ozone result from strong vertical shear in which the ozone between 5-8 km descends from the upper troposphere across the continental United States and the low ozone between 9-14 km originates from the tropical upper troposphere. The very low ozone between 5-15 km during days 09/02-09/08 is associated with trajectories transporting clean air from the Pacific Ocean.
Supplementary URL: http://vortex.nsstc.uah.edu/atmchem/pub/pubs.html