In this study we utilize potential vorticity - isentropic (PVI) coordinate transformations as a means of combining ozone data from different sources to construct daily, synthetic three-dimensional ozone fields. This methodology has been used successfully to reconstruct ozone maps in particular regions from aircraft data over the period of the aircraft campaign. We expand this method to create high-resolution daily global maps of profile ozone data, particularly in the lower stratosphere, where high-resolution ozone data are sparse. Ozone climatologies in PVI-space are constructed from satellite-based SAGE II and UARS/HALOE data, both of which use solar occultation techniques to make high vertical resolution ozone profile measurements, but with low spatial resolution. A climatology from ground-based balloonsonde data is also created. The climatologies are used to establish the relationship between ozone and dynamical variability, which is defined by the potential vorticity (in the form of equivalent latitude) and potential temperature fields. Once a PVI climatology has been created from data taken by one or more instruments, high-resolution daily profile ozone field estimates are constructed based solely on the PVI fields, which are available on a daily basis from NCEP analysis. These profile ozone maps could be used for a variety of applications, including use in conjunction with total ozone maps to create a daily tropospheric ozone product, as input to forecast models, or as a tool for validating independent ozone measurements when correlative data are not available.
This technique is limited to regions where the ozone is a long-term tracer and the flow is adiabatic. We evaluate the internal consistency of the technique by transforming the ozone back to physical space and comparing to the original profiles. Biases in the long-term average of the differences are used to identify regions where the technique is consistently introducing errors. Initial results show the technique is useful in the lower stratosphere at most latitudes throughout the year, and in the winter hemisphere in the middle stratosphere. The results are problematic in the summer hemisphere middle stratosphere due to increased ozone photochemistry, and in the tropics as a result of noisy meteorological fields and weak PV gradients. Alternate techniques in these regions will be discussed. An additional limitation is the quality and resolution of the meteorological data. This is discussed in a companion paper (Long, et al.)