196 Impact of Convection and Long-Range Transport on Short-Lived Halocarbons in the UT/LS

Monday, 8 January 2018
Exhibit Hall 3 (ACC) (Austin, Texas)
E. Atlas, Univ. of Miami, Miami, FL; and S. Schauffler, M. Navarro, R. Lueb, R. Hendershot, and R. Ueyama

Chemical composition of the air in the upper troposphere/lower stratosphere is controlled by a balance of transport, photochemistry, and physical processes, such as interactions with clouds, ice, and aerosol. The chemistry of the air masses that reach the upper troposphere can potentially have profound impacts on the chemistry in the near tropopause region. For example, the transport of reactive organic halogens and their transformation to inorganic halogen species, e.g., Br, BrO, etc., can have a significant impact on ozone budgets in this region and even deeper the stratosphere. Trace gas measurements in the region near the tropopause can also indicate potential sources of surface emissions that are transported to high altitudes. Measurement of trace gases, including such compounds as non-methane hydrocarbons, hydrochlorofluorocarbons, halogenated solvents, methyl halides, etc., can be used to characterize source emissions from industrial, urban, biomass burning, or marine origins. Recent airborne research campaigns have been conducted to better characterize the chemical composition and variations in the UT/LS region. This presentation will discuss these measurements, with a special emphasis on the role of convection and transport in modifying the budget of organic halogen species in the UT/LS.
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